常用的几种卡波姆

常⽤的⼏种卡波姆

Carbopol 940：短流变性、⾼粘度、⾼清澈度，低耐离⼦性及耐剪切性，适⽤于凝胶及膏霜中Carbopol 941：长流变性、低粘度、⾼清澈度，中等耐离⼦性及耐剪切，适⽤于凝胶及乳液

Carbopol ETD 2020：丙烯酸酯/C10-30烷基丙烯酸酯交链共聚物，长流变性、低粘度、⾼清澈度、⾼耐离⼦性及耐剪切性，适⽤清澈凝胶。

Carbopol AQUA SF-1：液体，长流变性、可配制清澈配⽅，与多种成份具优良的相容性，回酸增稠，可⽤于表⾯活性剂体系。

Carbopol Ultrez 21：丙烯酸酯/C10-30烷基丙烯酸酯交链共聚物，短流变性、⽤于凝胶、洗涤清洁⽤品、⾼电解质产品、膏霜、乳液。

Carbopol Ultrez 20：丙烯酸酯/C10-30烷基丙烯酸酯交链共聚物，长流变性、⾹波、沐浴凝胶、膏霜/乳液、含电解质的护肤、护发凝胶

Pemulen TR-1：丙烯酸酯/C10-30烷基丙烯酸酯交链共聚物，增稠型乳化剂、短流变性、⽤于膏霜、乳液Pemulen TR-2：丙烯酸酯/C10-30烷基丙烯酸酯交链共聚物，增稠型乳化剂、长流变性、⽤于乳液Carbopol ULTREZ 20聚合物Carbopol? Ultrez 20 Polymer

INCI Name: Acrylates/C10-30 Alkyl Acrylate Crosspolymer

Carbopol? Ultrez 20 polymer is a hydrophobically（疏⽔性地）modified cross-linked acrylate copolymer. This polymer offersmany substantial benefits for formulators and marketers of personal care products. Like other \"Ultrez\" grade polymers,Carbopol Ultrez 20 polymer is exceptionally easy to use - it self-wets and disperses within minutes.

This rheology （流变学）modifier and stabilizer also provides electrolyte tolerance（耐受性）and unique sensory benefits informulations. It can be used in systems with moderate surfactant content, making it an ideal choice for many applications.Key Benefits of Carbopol Ultrez 20 Polymer

Pleasing Sensorial（知觉的，感觉的）Properties: Carbopol Ultrez 20 provides a rich, creamy skinfeel during the

rubout（擦掉，抹掉）phase of applying oil-in-water based creams and lotions（洗液）. These properties are featured in ourSensiMap Formulating（明确叙述）Concept.

Rapid Wetting: The unique structure of Carbopol Ultrez 20 polymer allows for rapid wetting and improved swelling（膨胀）time without the need for agitation.

This processing benefit is offered without compromising the performance that the personal care industry expects from theCarbopol polymer product line.

Efficient Thickening（⾼效增稠）: Carbopol Ultrez 20 polymer provides moderate-to-high viscosity with smooth, long flowproperties. It's a versatile（通⽤的）product that can be used when your formulations require viscosity and

suspending properties. Carbopol Ultrez 20 polymer performs effectively across a broad pH range, making it a versatileingredient for many applications.

Stability of Ingredients in Surfactant-Containing Formulation s（配⽅）: In shampoo and body wash formulations, CarbopolUltrez 20 polymer helps to

suspend and stabilize beads（珠⼦，⽔珠）, microcapsules and exfoliants（去⾓质系列）for excellent product stability andvisual appeal（视觉的吸引⼒）. In 2-in-1 formulations, Carbopol Ultrez 20 polymer can stabilize silicone fluids and oilseffectively.

Aesthetic（美学的;审美的）Properties: Carbopol Ultrez 20 polymer exhibits good clarity（透明）in gel formulations, alongwith providing a smooth,

aesthetically pleasing gel（凝胶）quality. In creams and lotions（洗液）, it helps to create emulsions（乳剂）with excellentskin feel.

Excellent Clarity:Even at high polymer concentration, Carbopol Ultrez 20 polymer maintains superior clarity. It can be usedwith confidence（满怀信⼼地）in systems where sparkling（发泡的, 闪烁的）clarity is required.

Excellent Electrolyte（电解质）Tolerance:Viscosity, clarity and stability are all maintained in the presence of（在⾯

前）electrolytes with Carbopol Ultrez 20 polymer. It is ideally suited for use in formulations containing higher levels of oils,botanical（来⾃植物的; 植物的）ingredients, or humectants（湿润剂）like Sodium PCA.

Carbopol Ultrez 20 polymer provides excellent performance in a wide range of products, including:ShampoosLotionsBody washesHair and skin gelsBath gelsCreams

Carbopol? Ultrez 20 polymer is a featured ingredient in the SensiMap? Formulating Concept.Carbopol? Ultrez 20 polymer is recommended for hand sanitizer（消毒杀菌剂）gels.Name: CARBOPOL? ULTREZ 20 POLYMERCompany: Lubrizol Advanced Materials Asia 路博润Trade Name: CARBOPOL?

Description: Like other \"Ultrez\" grade polymers, Carbopol? Ultrez 20 polymer is exceptionally easy to use-it self wets anddisperses within minutes. This new thickener and stabilizer also provides improved electrolyte tolerance and unique sensorybenefits. It can be used in systems with a moderate surfactant content, making it an ideal choice for many applications.Documents Data SheetDATA SHEET(English)Technical Information

DISPERSION TECHNIQUES FOR CARBOPOL? POLYMERS(English)

FORMULATING HYDROALCOHOLIC（⽔醇的，氢醇） GELS W ITH CARBOPOL? POLYMERS(English)HOW TO PREPARE AQUEOUS DISPERSIONS OF CARBOPOL? POLYMERS(English)

NEUTRALIZING CARBOPOL? AND PEMULEN? POLYMERS IN AQUEOUS AND HYDROALCOHOLICSYSTEMS(English)

Product name : Carbopol Ultrez 21 Polymer

Chemical name : Acrylates/C10-30 alkyl acrylate crosspolymerItems Properties

Appearance：white powderOdor：mild acrylic odorTotal solids：100%pH (in water)： 30.5% mucilage（粘液）

viscosity at 20 rpm：55, 000 mPa?·s

0.5% dispersionwetting time： 3 minutes0.5% mucilage* clarity(% Transmission)（传送）~ 95Characteristics and Application :

Carbopol Ultrez 21 Polymer is a hydrophobically(疏⽔性地) modified crosslinked

polyacrylate polymer designed to efficiently impart(赋予)thickening, stabilizing, and suspending properties to a variety ofpersonal care applications.

Carbopol Ultrez 21 polymer is self wetting crosslinked polyacrylic acid polymer that is synthesized in a cosolvent(共溶剂)ethylacetate/cyclohexane mixture.It provides greater versatility(多功能,多⽤途) in formulating because it quickly and easily selfwets without any mixing required. Carbopol Ultrez 21 polymer has short flow characteristics with relatively high viscositycompared to other Carbopol polymers. Benefits :

Facilitates(使容易) formulating and processing because it is a self-wetting polymer that requires no dispersion agitation.Provides excellent thickening efficiency to form very high clarity gels.

Provides shear(切变) thinning(变稀) rheology(流变能⼒)to enable easy pumping(抽吸)and dispensing(分发; 分配)of finishedproducts via trigger(扳柄)sprayers(喷雾器). Provides yield value(屈服值)to allow for the suspension of a wide variety of

insoluble materials or particles(粒⼦). Yield value enables finished products to have vertical cling(附着)which is an importantcharacteristic for products that are dispensed via a trigger spray(反柄喷雾器) or nozzle(管⼝, 喷嘴).Stabilizes oil-in-water emulsions.

INCL命名：丙烯酸酯/C10-30烷基丙烯酸酯交联聚合物（Acrylates/C10-30 Alkyl Acrylate Crosspolymer）⼀．⼯艺操作上的优点：

在⼯艺操作上ULTREZ 20⽐ETD2020更简便。

快速润湿：⾃我润湿-分散时⽆须搅拌！与Carbopol ULTREZ 20和10相似的润湿性质。更不易引⼊⽓泡。

稳定的聚合物溶涨性能：分散液粘度更稳定；应⽤性能更稳定。凝胶的外观更平滑。可以采⽤后中和。

Carbopol聚合物的润湿时间性（25℃时

Carbopol聚合物润湿时间 0.5wt%(分钟) 润湿时间 3.0wt%(分钟) Ultrez 20 3 5Ultrez 21 2-3 5Ultrez 10 5 6ETD2020 20 >3hr980 >50 >5hr

⼆. ⼯艺操作和配⽅应⽤指南:

将聚合物撒向⽔⾯,让其⾃我润湿(剧烈的搅拌会产⽣⽓泡).开始缓慢的搅拌.

Ultrez 20采⽤先中和,后中和均可(视具体⽽定).

加⼊其它配⽅组分,其间搅拌应尽可能的慢(以避免引⼊⽓泡).

三. 性能上的优点:

与ETD2020 Polymer相似的性能:●耐电解质出⾊:

能增稠常见的阴离⼦,两性离⼦或⾮离⼦表⾯活性剂体系.能增稠含电解质的凝胶或乳液.

芦荟,吡咯烷酮羧酸钠(PCA-Na),植物提取物等等.●屈服值⾼:

能悬浮不溶性的颗粒: 粒珠,ZPT等等.能稳定不溶性的硅氧烷和油脂.能稳定乳化液.

●较⾼粘度,同时具有剪切变稀的流变学性质.⽐ETD2020 Polymer更好的性能:●添加后的透明度更好.产品透明度的指标已因此更新.●能溶忍的表⾯活性剂的含量更⾼.●制得的凝胶,其外观更平滑,更有光泽.

四. 粘度与浓度的关系: PH=6.0-7.5 Brookfield RVT@20rpm.

Ultrez 20与ETD2020的粘度-浓度曲线相近,⽽Ultrez 21的粘度-浓度曲线更陡峭.五. NaCl对Carbopol聚合物凝胶粘度的影响: 1.0wt%,PH7.5 Brookfield RVT@20rpm

Ultrez 20与ETD2020的粘度-NaCl浓度wt%曲线相近,⽽Ulrez 21的粘度-NaCl浓度wt%曲线的下降斜率要更⼤.六. 应⽤推荐:◆⾹波: 去头屑,⼆合⼀.◆沐浴凝胶: 保湿,悬浮粒珠.◆奶液/膏霜: 含电解质.◆肤⽤凝胶: 含电解质(芦荟).◆发⽤凝胶.◆消毒洗⼿液.

七. Carbopol Ultrez 20聚合物优点总结:●快速⾃我润湿,分散⽆需搅拌.●稳定表⾯活性剂体系配⽅.

能很好地稳定8-12wt%表⾯活性剂含量的配⽅.

●稳定,悬浮不溶性组分(例如⼆甲基硅氧烷,油类,ZPT,粒珠等等.)●稳定含电解质的配⽅.●外观平滑⽽具美感.

Carbopol Ultrez 20聚合物在配⽅中的应⽤

引⼦: 如何选择Carbopol聚合物?

●Ultrez 20,ETD2020,Ultrez 21,液体状聚合物(例如Carbopol Aqua SF1)之间优点的⽐较:

在含电解质的⾼粘度溶胶中.

在含电解质的膏霜或奶液(⽔包油型乳化体系).在表⾯活性剂体系的清洁产品中(例如⾹波,沐浴凝胶)⼀. 免洗型凝胶:对⽐项⽬测试⽤配⽅-粘度 -Carbopol聚合物 0.8%-透明度 -芦荟(40:1) 2.5%-防腐剂

配⽅PH为7.0,含电解质–⾹精-NaOH测试结果:

电解质含量⾼的⽔凝胶中,ULTREZ 20更有效.

与ETD2020⽐较,ULTREZ 20能赋予相似的透明度和更⾼的粘度.使⽤ULTREZ 20时,再添加1%Copolyol-1并不会产⽣增益.⼆. 乳化型膏霜和奶液:粘度⽐较测试⽤配⽅

⾼含量电解质(有机和⽆机)⾯军 -Carbopol聚合物 0.4%的膏霜和奶液,添加了ULTREZ 20, -⽩油 8U21或ETD2020. –A 165(GMS acid stable) 1-⼗六醇 0.5PH=6.0 -丙⼆醇 2-Ultrasil DW-18 0.3-防腐剂-NaOH

PCA-Na,泰国野葛根或纸桑树.

测试结果(1): 在膏霜配⽅中,⽆机电解质的影响:

不含电解质时,U21能赋予最⾼的粘度,但是,ULTREZ 20,ETD2020耐电解质能⼒⽐U21更好.⾼含量电解质的条件下,ULTREZ 20耐电解质能⼒最好.测试结果(2): 在膏霜配⽅中,有机电解质的影响:

在膏霜配⽅中有机电解质对粘度的影响,取决于该电解质为何物.ULTREZ 20,ETD2020耐电解质能⼒相似.三. 表⾯活性剂体系的透明⾹波,沐浴凝胶:粘度,透明度,屈服值对⽐: 测试⽤配⽅

添加ULTREZ 20,ETD2020或Aqua SF-1 -Carbopol聚合物的透明⾹波,沐浴凝胶 ULTREZ 20或ETD2020 1.2%或Aqua SE-1 6.0% -SLE(2)S 8-16PH=5.5,6.5,7.5 -CAPB 2-防腐剂-NaOH测试结果：

透明表⾯活性剂体系: 在低PH(PH=5.5)和表⾯活性剂含量⾼的条件下，Aqua SF-1被证实最有效，这是因为其回酸增稠效应以及它与表⾯活性剂的协同增效作⽤所致。

在8%的表⾯活性剂含量的条件下，ULTREZ 20能赋予很好的增稠功效和透明度。表⾯活性剂含量更⾼时，ULTREZ 20的功效和透明度将受影响。

透明表⾯活性剂体系:在PH=6.5时,Aqua SF-1能体现最佳的透明度,但需要更⾼的添加量以增加粘度和悬浮能⼒.ULTREZ 20与ETD2020流变学性质相似,ULTREZ 20透明度更好.

透明表⾯活性剂体系:在PH=7.5时,ULTREZ 20体现了最好的流变学性质.ULTREZ 20的透明度⽐ETD2020稍好些.Aqua SF-1透明度很好,然⽽要达到⾜够的增稠和悬浮,其添加量需要增加.

透明⾹波,沐浴露: 盐对粘度的影响-ULTREZ 20/ETD2020: 在所有条件下,ULTREZ 20和ETD2020性能相似,在中性PH和较低表⾯活性剂下,⼆者的耐盐能⼒更强.

透明⾹波,沐浴凝胶(盐对透明度的影响—ULTREZ 20,ETD2020):5.5-7.5PH范围内,表⾯活性剂含量较低,则可得到更好的透明度.与ETD2020相⽐较,ULTREZ 20性能更好.

透明⾹波,沐浴露: 盐对屈服值的影响-ULTREZ 20/ETD2020:在所有测试的PH

下,ULTREZ 20与ETD2020性能相似.在中性PH和较低表⾯活性剂下,⼆者的耐盐能⼒更强.

透明⾹波,沐浴凝胶(盐对粘度的影响—Aqua SF-1): Aqua SF-1的增稠功效如下关联因素⽽增强: 阴离⼦表⾯活性剂含量>12%,适当的含盐量,较低的PH(PH=5.5).Aqua SF-1添加量为6%.

透明⾹波,沐浴凝胶(盐对透明度的影响—Aqua SF-1): PH>6时,可得到最佳的透明度.PH较低时,若表⾯活性剂含量较⾼,则能得到更好的透明度. Aqua SF-1添加量为6%.

透明⾹波,沐浴凝胶(盐对屈服值的影响--Aqua SF-1): 较⾼的含盐量,通常能有助于提⾼屈服值. Aqua SF-1添加量为6%.在透明表⾯活性剂体系中,ULTREZ 20与Aqua SF-1的⽐较: 实验所⽤的SLE2S添加量范围内,PH=5.5,6.5时,ULTREZ 20在⾹波中并未展现出最佳性能; ⽽在PH=7.5时我们发现,含ULTREZ 20与⾹波对⾼含量电解质表现得⾮常好.

在PH相似时,ULTREZ 20的粘度性能与Aqua SF-1相似.因⽽可以这么说,就象Aqua SF-1体系⼀样,在⾼含量电解质的情况下协同增稠效应发⽣了.

透明表⾯活性剂体系中Carbopol选⽤指南:配⽅基准:

-粘度过 3-15000mPa.s-透明度 >80%-屈服值 100

●Ultrez 20配⽅: 推荐使⽤6-10%SLES和2%甜菜碱(<0.3%盐)

Ulrez 20与ETD2020使⽤性能对⽐测试总结◆透明度:

所有测试中,Ultrez 20透明度较好.◆粘度:

⼤多数测试中,Ultrez 20粘度较⾼.◆屈服值:⼆者相当.◆外观的美感,平滑:

Ultrez 20制得的凝胶,乳液平滑,有光泽.◆应⽤的⼴泛度:

能应⽤于凝胶,奶液,膏霜,⾹波,沐浴露,且性能出⾊.有关法规⽅⾯的情况

◆INCL命名: 丙烯酸酯/C10-30烷基丙烯酸酯交联聚合物(Acrylates/C10-30alkyl acrylate crosspolymer)

◆注册:美国，欧洲，⽇本，加拿⼤，韩国，中国，澳⼤利亚，菲律宾．◆符合EU Cosmetics Directive 76/768.◆⽇本INCL命名: 已按要求申请得到.产品规范(暂⾏)

红⾊所⽰为不同于ETD2020的新指标

⽔温对润湿时间的影响-0.5wt%: 推荐分散温度: 25-50℃(注意: 若在60-70℃分散Ultrez 20,会出现为分散好的⼤颗粒.⽔温对润湿时间的影响-3.0wt%: 推荐分散温度: 25-50℃ETD2020的润湿时间:>2hr

聚合物浓度对分散液粘度的关系: 分散液粘度随聚合物浓度的加⼤⽽加⼤.

PH对粘度的影响(Carbopol聚合物-0.5wt%, NaOH-18wt%): 粘度先是随PH的加⼤⽽加⼤,约在PH5.3时粘度达到最⼤值,然后随着PH的加⼤粘度下降.

PH对屈服值的影响: (Carbopol聚合物-0.5wt%, NaOH-18wt%): 屈服值先是随PH 的加⼤⽽加⼤,约在PH5.3时屈服值达到最⼤值,然后随着PH的加⼤屈服值下降,⾄PH10以上后趋于恒定值.聚合物的浓度加⼤时,粘度和屈服值均相应加⼤.

PH对透明度的影响: PH在5-11的较宽范围内透明度均处于较⾼值,⽽在PH<5和PH>11时则透明度下降明显.

聚合物浓度对透明度的影响:在Carbopol聚合物的浓度在0.1-0.5wt%时,透明度基本⽆变化,当聚合物浓度⼤于0.5wt%时,透明度随着聚合物浓度的加⼤⽽呈现出较明显的下降趋势.

外观: 悬浮彩⾊粒珠,稠厚的透明液体. PH: 5.7-6.0粘度(mPa.s): 4,000-6,500屈服值(dyn/cm 2

): 250-450 浊度(NTU): 15-25

稳定性: 通过”3个⽉,45℃”的试验.通过5个轮次的循环实验. Carbopol Ultrez 20聚合物的活性物含量(%): 1.0 表⾯活性剂含量(%):9.8 制备:

1. 将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯,待U20完全润湿,然后开始慢慢搅拌10分钟.2.

缓慢搅拌下,依次加⼊Standapol ES-2和EA-2. 3. 加⼊NaOH 部分中和⾄PH4.8.4. 将B 相各组分混合后,将其加⼊A 相中.5. 加⼊已经混合溶解的C 相,搅拌⾄均匀.6. 加⼊DMDMhydantoin.7. 加⼊NaOH 中和⾄PH5.8.

8. 缓慢搅拌下,加⼊Unispheres.

性质：

外观：Light Green Pearlescent liquidPH: 5.5-5.7

粘度(mPa.s): 4,500-7,000屈服值(dyn/cm2): 200-400

稳定性: 通过”3个⽉,45℃”的试验.通过5个轮次的循环实验.Carbopol Ultrez 20聚合物的活性物含量(%): 0.85表⾯活性剂含量(%): 11.1制备:

1.在有夹套冷凝加热的搅拌釜内,将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯(40-50℃),待U20完全润湿,然后开始慢慢搅拌10分钟.2.缓慢搅拌下,加⼊A相.

3.加⼊已在另⼀容器中分散好的⽠⽿胶,加热⾄75℃.4.加⼊C相,72℃下⾄溶解均匀,然后开始冷却.5.加⼊已好的云母,搅拌⾄均匀,继续冷却⾄40℃.

6.在另外⼀容器中如此混合E相各组分: 先将组分12加⼊11中,混合⾄均匀;然后加⼊其它组分混合⾄均匀.待主搅拌釜冷⾄40℃时,加⼊E相.7.加⼊颜料,混合均匀.

8.加⼊NaOH中和⾄PH5.6,混合⾄均匀.

含蜂蜜和杏仁的沐浴液(Carbopol Ultrez 20聚合物,植物提取物,油

性质：

外观：半透明液体PH: 6.0-6.2

粘度(mPa.s): 6,500-9,500屈服值(dyn/cm2): 300-500

稳定性: 通过”3个⽉,45℃”的试验.通过5个轮次的循环实验.Carbopol Ultrez 20聚合物的活性物含量(%): 0.50表⾯活性剂含量(%): 14.0制备:

1. 在有夹套冷凝加热的搅拌釜内,将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯(50℃),待U20完全润湿,然后开始慢慢搅拌10分钟.加⼊A相中的⽉桂基醚硫酸钠,保持50℃.

2.在另外⼀容器中,⽔平线合B相各组分⾄均匀,加热⾄50℃.(注意:组分6和7须在30-35℃加⼊B相,且搅匀后⽅可随B相加⼊主搅拌釜).将B相加⼊主搅拌釜,混合均匀后开始冷却.3.依次加⼊C相各组分,混合均匀.

4.在另外⼀容器中,混合D相各组分⾄均匀.待主搅拌釜冷⾄50℃时,加⼊D相.5.⽤NaOH中和⾄PH6.1,混合均匀.

含⼗六烷基三甲基氯化铵的透明调理性发胶(Carbopol Ultrez 20和Fixate

性质:

外观: 透明凝胶.PH: 5.8-6.2

粘度(mPa.s): 8,500-13,000浊度(NTU): 2-15

稳定性: 通过”3个⽉,45℃”的试验.通过5个轮次的循环实验.⾼湿度下卷曲保持率(%): 83%, 8⼩时后82%, 24⼩时后

Fixate G-100聚合物含固率(%): 1.0

* Brookfield RVT@20rpm#5转⼦,24⼩时后,25℃时测量.** Micro 1000 or DRT 100B Turbidmeter(HF Scientific)*** 90%相对湿度,25℃制备:

1.将EDTA⼆钠加⼊温热的去离⼦不(~40℃),搅拌⾄溶解.

2.将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯,待U20完全润湿,然后开始慢慢搅拌10分钟.

3.加⼊Fixate G-100聚合物,搅拌⾄均匀..4.⽤AMP-95中和⾄PH6.0.5.混合B相后,加⼊⾄A相.

6.缓缓加⼊已混合好的C相,搅拌⾄均匀.7.加⼊DMDM Hydantoin,搅拌⾄均匀.8.若有必要,调节最终PH⾄6.0.

外观: Creamy white emulsion.PH: 5.8-6.1

粘度(mPa.s): 6,000-12,000屈服值(dyn/cm2): 700-1,000

稳定性: 进⾏中:已过1个⽉,45℃” 5个轮次循环实验.* Brookfield RVT@20rpm#5转⼦,24⼩时后,25℃时测量.制备:

1. 将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯(~45-50℃),待U20完全润湿,然后开始慢慢搅拌10分钟.2.加⼊⽢油,加热⾄60℃.

3.在另外⼀容器中,混合B相各组分,60℃⾄均匀.然后将B相加⼊主搅拌釜,搅拌⾄均匀(~10-15分钟),尔后开始冷却.

4.待<50℃时,加⼊C相各组分,搅拌⾄均匀.

5.待<45℃时,加⼊乳酸钠,Germaben llE,搅拌⾄均匀.6.⽤NaOH中和⾄PH5.8-6.1,混合均匀.

“Damage Control”抗衰⽼乳液(Carbopol Ultrez 20聚合物,植物提取

性质:

外观: 奶油状,淡黄⾊乳液.PH: 5.5-6.0

粘度(mPa.s): 6,000-9,000

稳定性: 进⾏中:已过1个⽉,45℃” 5个轮次循环实验.

* Brookfield RVT@20rpm#5转⼦,24⼩时后,25℃时测量. 24hours,25℃制备:

1. 将Carbopol Ultrez 20聚合物撒向去离⼦⽔的⽔⾯(~45-50℃),待U20完全润湿,然后开始慢慢搅拌.

2.加⼊⽢油,加热⾄75℃.

3.在另外⼀容器内,混合B相各组分,加热⾄75℃,搅拌均匀后加⼊主搅拌釜(500rpm).4. 在另外⼀容器内,混合C相各组分,然后加⼊主搅拌釜,搅拌⾄均匀(约~10分钟).5. Homogenize with⽤Ultra Turrax(注:制造商: lka)均质器(或类似均质器)以22,000rpm

均质45分钟,然后开始冷却.(注意: 均质时间取决于均质器类型和料液量,均质时间不要过长,以免造成粘度丧失).6. ⽤NaOH中和⾄PH6.0.因粘度上升,可提⾼搅拌速度(500-1500rpm).搅拌⾄均匀.7. 待主搅拌釜冷⾄<45℃时,加⼊Phenonip.8. 依次加⼊其余各个配⽅组分,搅拌⾄均匀.(End)

Carbopol AQUA SF-1

Carbopol? Aqua SF-1 Polymer 卡波SF-11.INCI Name: Acrylates Copolymer2.INCI名称：丙烯酸类聚合物3.CAS号:68083-14-7Carbopol? Aqua SF-12010-01-21 10:19

Carbopol? Aqua SF-1 Polymer卡波SF-11. INCI Name: Acrylates Copolymer

INCI名称：丙烯酸类聚合物， CAS号:68083-14-72. As Supplied产品数据

2.1 Appearanc: milky, white liquid外观：乳⽩⾊⾄⽩⾊液体2.2 Odor:mild acrylic⽓味：略有丙烯酸⽓味

2.3 Total Solids (by weight): 30%总固体：≥30.0%2.4 Specific Gravity: 1.05相对密度：1.05g/ml±0.012.5 pH: 3PH：2-4

2.6 Viscosity(Brookfield LV at 60 rpm ) :10 mPa.s粘度（LV转⼦，60转速）：≥10 mPa.s2.7 Residual Ethyl Acrylate (total, ppm) < 1.0丙烯酸⼄酯残留：≤1.0mg/kg

2.8 1% Active Polymer in Water, pH 7.51%丙烯酸聚合物⽔溶液（PH7.5）：

Viscosity( Brookfield RVT at 20 rpm) 4,500 mPa.s粘度（RVT转⼦，20r/min）：4,500 mPa.sViscosity (0.2 wt% NaCl) 700 mPa.s粘度（0.2%氯化钠溶液）：700 mPa.sTurbidity 35 NTU混浊度：35 NTU3 Shelf Life: 36 months

保质期：36个⽉

------摘⾃Lubrizol Advanced Materials Asia 路博润（收购了诺誉）产品数据表

液体，长流变性、可配制清澈配⽅，与多种成份具优良的相容性，回酸增稠，可⽤于表⾯活性剂体系。INCL: 丙烯酸共聚物交联的丙烯酸共聚物聚合⽅式: 乳液聚合.物理性质:外观: ⽩⾊乳状液.粘度(mPa.s): 10聚合物的含量,%: 30密度: 1.05g/mlPH: 3.0

残余单体(总量): <20ppm

1%活性物在⽔中.PH7.5 粘度,mPa.s: 4500粘度0.2%NaCl,mPa.s: 700浊度(NTU): 35

Carbopol? Aqua SF-1 PolymerINCI Name: Acrylates Copolymer

Carbopol? Aqua SF-1 polymer is a lightly cross-linked acrylate copolymer. It is a novel, liquid, acrylic rheology modifierdesigned to suspend, stabilize, thicken, and enhance the appearance of surfactant-based personal cleansing products andsoap-based cleansing systems.

Carbopol Aqua SF-1 polymer is a cost-effective and easy-to-use product that provides numerous benefits.Key Benefits of Carbopol Aqua SF-1 Polymer

Easy-to-Use Liquid Form: Carbopol Aqua SF-1 polymer is supplied as a low viscosity liquid that is easily and quicklyincorporated into a formulation.

Suspension and Stabilization: Carbopol Aqua SF-1 polymer provides excellent suspending and stabilizing properties in avariety of surfactant-based

cleansing products; even low viscosity formulations. Insoluble and

difficult-to-stabilize ingredients such as silicones can be easily co-emulsified andstabilized.

Thickening and Flow Control: Carbopol Aqua SF-1 polymer imparts effective thickening and desirable flow characteristics toshampoos, body washes andother cleansing formulations.

Clear Formulations: Carbopol Aqua SF-1 polymer permits the formulation of high clarity shampoos, body washes and othercleansing products.

pH Flexibility: Carbopol Aqua SF-1 polymer is effective over a wide pH range: from 3.5 to 10.0 (or higher). The polymerdisplays a unique ability to provide

increased suspending, stabilizing and thickening benefits upon acidification afterinitial neutralization, a phenomenon known as “Back-Acid” thickening.

Surfactant Compatibility: Carbopol Aqua SF-1 polymer is compatible with virtually all commercial nonionic, anionic and

amphoteric surfactants as well as

with a wide array of popular additives and conditioning agents, such as cationicpolymers.

Synergistic Thickening with Salt and Surfactants: Carbopol Aqua SF-1 polymer functions synergistically with salts andsurfactants providing options for

achieving various suspending, stabilizing and thickening requirements.

Enhanced Pearlization: Carbopol Aqua SF-1 polymer has the remarkable ability to enhance the visual impact of mica andother pearlizing additives used in surfactant-based systems.

Carbopol? Aqua SF-1 polymer is recommended for anti-bacterial hand soapsCarbopol? Aqua SF-2 Polymer

INCI Name: Acrylates Crosspolymer-X (proposed)

Enabling low pH, high clarity cleansers with food grade preservative claims.Due to the increasingly negative perception of paraben and formaldehyde donor type

preservatives, the personal care market is shifting toward the use of food grade preservatives like Sodium Benzoate. Thesenatural preservatives require a pH level near 5.0, which sacrifices desired formulation clarity and flow properties when usingcurrently available rheology modifiers. Carbopol? Aqua SF-2 polymer responds to this market trend by offering rheologymodification that delivers high clarity and superior suspension in the 4 to 6 pH range. Now formulators can display colorfulbeads, sparkling pearls, and exfoliating scrubs while also achieving claims of “paraben-free,” “formaldehyde-free,”“preservative-free,” and even “skin neutral pH”.Key Formulation Benefits

Elegant rheology with smooth, honey-like flowVery clear surfactant formulations at pH 4 to 6

Ideal for use with food grade preservatives such as Sodium Benzoate and Sorbic AcidHigh suspension and stabilization of insoluble ingredients, including silicone, oils, emollientspH flexibility with “Back-Acid” formulating techniqueBroad surfactant compatibilitySynergistic thickening with saltEnhances pearlescent appearance

Stabilizes high oil-loaded body wash emulsions

Compatible with low levels of cationic conditioning ingredientsEasy-to-use liquid form; cold processBroad Applications Fit

Clear bath gels, shampoos and cleansersPearlescent body washes and shampoosBody scrubs with suspended microcapsulesFacial scrubs with exfoliating beadsAnti-acne facial cleansers with salicylic acidConditioning shampoos